Accession Number : ADA262821


Title :   Novel Gas Phase Ion Molecule Reactions of C60 ++ with O2


Descriptive Note : Technical rept.


Corporate Author : STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY


Personal Author(s) : Stry, James J ; Garvey, James F


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a262821.pdf


Report Date : 03 Apr 1993


Pagination or Media Count : 22


Abstract : The gas phase ion-molecule chemistry of doubly charged fullerene cations (C(n)++ where n=46,48,...60 and 70) with neutral oxygen molecules, were investigated using a triple quadrupole mass spectrometer. In this paper, we report additions to the fullerene cage structure which result in the formation of C(n)O++, C(n)O2++, and C(n)O3++ product ions from the C(n)++ reagent ion. In addition, we also report charge transfer reactions resulting in the production of C(n)+ and 02+ ions, as well as reactive charge transfer reactions generating C(n)O+ and 03+. All of these processes are a result of low energy ion-molecule collisions (0.1-24.5 eV sub lab). The normalized intensity of the fullerene products exhibit little dependence on size of fullerene clusters examined. However, the reactivities of the fullerenes are found to be highly dependent on the collision energy and the oxygen pressure within the collision cell.


Descriptors :   *ION MOLECULE INTERACTIONS , IONS , CATIONS , PRODUCTION , MOLECULES , NEUTRAL , CELLS , ENERGY , STRUCTURES , INTENSITY , REACTIVITIES , FULLERENES , CARBON , PHASE , GASES , OXYGEN , CHEMISTRY , LOW ENERGY , PRESSURE , CHARGE TRANSFER , MASS SPECTROMETERS , TRANSFER , SPECTROMETERS , COLLISIONS


Subject Categories : Inorganic Chemistry
      Physical Chemistry
      Atomic and Molecular Physics and Spectroscopy


Distribution Statement : APPROVED FOR PUBLIC RELEASE