Accession Number : ADA261496


Title :   The Development of New Protecting/Leaving Groups and Application to the Synthesis of Cage Nitramines


Descriptive Note : Final rept.


Corporate Author : SRI INTERNATIONAL MENLO PARK CA


Personal Author(s) : Schmitt, Robert J ; Bottaro, Jeffrey C ; Penwell, Paul E


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a261496.pdf


Report Date : 05 Jan 1993


Pagination or Media Count : 110


Abstract : In the course of this study, we have accomplished the synthesis of a new, stable class of dinitramide salts that will have both fundamental scientific interest and practical applications. We have also developed a new type of condensation reaction for the synthesis of cage compounds and prepared new clathrates of CL-20 with significantly more energy than pure CL-20. The dinitramide salts are based on a newly discovered inorganic anion known as the dinitramide anion, N(NO2)(-) sub 2. The dinitramide anion is a uniquely stable, high oxygen density grouping that can be prepared in many different combinations, including the ammonium salts.


Descriptors :   *SYNTHESIS(CHEMISTRY) , *NITRAMINES , CRYSTAL STRUCTURE , CESIUM , OXYGEN , SULFONATES , SULFUR , SALTS , PHENYL RADICALS , ANIONS , SULFAMATES , HYDRAZINE DERIVATIVES , PHOSPHATES , CONDENSATION , ACIDS , ALDEHYDES , HYDROXYL RADICALS , ETHANES , RINGS , METHANE , AMMONIUM COMPOUNDS , ORGANIC COMPOUNDS , NITROGEN , METHYL RADICALS


Subject Categories : Inorganic Chemistry
      Organic Chemistry
      Physical Chemistry


Distribution Statement : APPROVED FOR PUBLIC RELEASE