Accession Number : ADA259219


Title :   Spectroscopic and Structural Properties of Binuclear Platinum- Terpyridine Complexes


Descriptive Note : Technical rept.,


Corporate Author : CALIFORNIA INST OF TECH PASADENA DIV OF CHEMISTRY AND CHEMICAL ENGINEERING


Personal Author(s) : Bailey, James A ; Miskowski, Vincent M ; Gray, Harry B


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a259219.pdf


Report Date : Aug 1992


Pagination or Media Count : 12


Abstract : Binuclear platinum-terpyridine (tpy) complexes have been prepared with a variety of bridging ligands resulting in a range of metal-metal distances (2.998(2) to 3.342(3) A). The energy of an intense visible absorption is strongly dependent on this metal-metal separation and is assigned to a d sigma *(Pt2) yield pi*(tpy) transition.


Descriptors :   *PLATINUM , METALS , COMPLEX COMPOUNDS , SPECTROSCOPY , STRUCTURAL PROPERTIES , ABSORPTION , PYRIDINES , PYRAZOLES , INDOLES , BRIDGES , TRANSITIONS , ENERGY , LIGANDS , SEPARATION


Subject Categories : Inorganic Chemistry
      Organic Chemistry
      Physical Chemistry
      Atomic and Molecular Physics and Spectroscopy


Distribution Statement : APPROVED FOR PUBLIC RELEASE