Accession Number : ADA258893


Title :   Structure of Trimethylplatinum(IV) with a Tripod Ligand


Descriptive Note : Technical rept.


Corporate Author : CALIFORNIA INST OF TECH PASADENA DIV OF CHEMISTRY AND CHEMICAL ENGINEERING


Personal Author(s) : Marsh, Richard E ; Schaefer, William P ; Lyon, David K ; Labinger, Jay A ; Bercaw, John E


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a258893.pdf


Report Date : Sep 1992


Pagination or Media Count : 20


Abstract : The trimethylplatinum (IV) completes octahedral coordination by bonding to three oxygen atoms of the tripod shaped methoxy Klaeui ligand. There are two independent molecule has normal bond distances and angles; Pt-c = 2. 001(11) Angstrom and Pt-O = 2.73(5) Angstrom. Many distances in the disordered molecule are uncertain, particularly in the areas of the C sup p carbon atom s and the CH3 groups, which overlap in the two orientations.


Descriptors :   *METHYL RADICALS , *LIGANDS , *PLATINUM , ACTIVATION , MOLECULES , ORGANOMETALLIC COMPOUNDS , CARBON , ALKANES , CHEMICAL BONDS , CHLORIDES , COMPLEX IONS , COBALT , CYCLIC COMPOUNDS , MOLECULAR STRUCTURE , SYMMETRY , HYDROCARBONS , OXYGEN , SATURATION , ATOMS , STRUCTURES , CRYSTAL STRUCTURE


Subject Categories : Organic Chemistry
      Physical Chemistry
      Crystallography


Distribution Statement : APPROVED FOR PUBLIC RELEASE