Accession Number : ADA258271


Title :   Some Useful Bis(trimethylsilylamino)silanes (Preprint)


Descriptive Note : Technical rept.


Corporate Author : MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY


Personal Author(s) : Mignani, Gerard ; Seyferth, Dietmar


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a258271.pdf


Report Date : 02 Nov 1992


Pagination or Media Count : 9


Abstract : For the preparation of cyclic silametallaazanes of type 1 in particular those in which R is a reactive substituent such as H or CH2=CH, we required the corresponding bis(trimethylsilylamino) silanes. Such compounds, we found, could be prepared readily by a Me3Si-for-H rearrangement reaction first reported by Wannagat and Niederprum in 1961.


Descriptors :   *ORGANOMETALLIC COMPOUNDS , *SILANES , METHYL RADICALS , NITROGEN , CHLORINE COMPOUNDS , SILICON COMPOUNDS , HYDROGEN , LITHIUM


Subject Categories : Inorganic Chemistry
      Organic Chemistry


Distribution Statement : APPROVED FOR PUBLIC RELEASE