Accession Number : ADA257049


Title :   Gallium and Indium Compounds Containing Three Different Substituents. Crystal and Molecular Structure of ((Me sub 3 CCH sub 2)ClGaPPh sub 2) sub 3


Descriptive Note : Technical rept.


Corporate Author : STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY


Personal Author(s) : Beachley, Jr , O T ; Maloney, John D ; Rogers, Robin D


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a257049.pdf


Report Date : 28 Oct 1992


Pagination or Media Count : 28


Abstract : Three new heavier group 13 element compounds containing three different substituents, (Me3CCH2)ClGaPPh2, (Me3CCH2)BrGaPPh2 and (Me3CCH2) ClInPPh2, have been prepared and characterized. All compounds were characterized by partial elemental analysis, cryoscopic molecular weight studies in benzene solution, and NMR and IR spectroscopic data. All three compounds exist as trimeric molecules in solution. NMR spectral data were consistent with the presence of multiple isomers of the trimers. The compound (Me3CCH2)ClGaPPh23 crystallizes in the acentric space group Pn2la with a = 17.741(9)A, b = 13. 942(6)A and c = 21.574(8)A. Diffraction data were collected on an Enraf-Nonius CAD-4 diffractometer, and the structure was refined to R = 4.6% and wR = 6.0% for those 2971 reflections with F0 less then or equal to 5 Sigma(F0). Gallium- phosphide, gallium chemistry, X-ray structural study.


Descriptors :   *CRYSTAL STRUCTURE , *GALLIUM , *MOLECULAR STRUCTURE , *INDIUM , BENZENE , METHYL RADICALS , MOLECULES , MOLECULAR WEIGHT , STRUCTURES , REFLECTION , DIFFRACTOMETERS , SUBSTITUTION REACTIONS , GALLIUM PHOSPHIDES , PHOSPHIDES , X RAYS , ISOMERS , CHEMISTRY , DIFFRACTION , LIGANDS , WEIGHT


Subject Categories : Inorganic Chemistry
      Organic Chemistry
      Atomic and Molecular Physics and Spectroscopy


Distribution Statement : APPROVED FOR PUBLIC RELEASE