Accession Number : ADA236202


Title :   Alkyl Azides, Diazides, Haloazides and Bridged Polycyclic Diazides


Descriptive Note : Final rept. 1 Jul 1989-14 Nov 1990,


Corporate Author : ILLINOIS UNIV AT CHICAGO CIRCLE


Personal Author(s) : Moriarty, Robert M


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a236202.pdf


Report Date : 16 May 1991


Pagination or Media Count : 35


Abstract : A series of monoazido alkanes and diazido alkanes have been synthesized. Specifically,1-azidobutane (100.0 g), 1-azidohexane (100.0 g), 1- azidooctane (100.0 g), and 1-azidoheptane (100.0 g), 1,3-diazidopropane (200.0 g), 1,4-diazidobutane (200.0 g, 1,5-diazidopentane (200.0 g), 1,6-diazidohexane (200.0 g), 1,7-diazidoheptane (200.0 g), 1,8-diazidooctane (200.0 g) were synthesized and characterized completely both analytically and spectroscopically. Among cyclic examples 1,2-diazidocyclopentane, 1,2- diazidocyclopentane, 1,2-diazidocyclohexane and 1,4-diazocyclohexane were synthesized. Norbornene was converted into a regioisomeric mixture of 2,3- diazido and syn and anti-2,7- diazidonorbornanes. The photodimer of nonbornadiene was synthesized and converted to the tetraazido analog.


Descriptors :   *ALKANES , AZIDES , ALKYL RADICALS


Subject Categories : Organic Chemistry


Distribution Statement : APPROVED FOR PUBLIC RELEASE