Accession Number : ADA191081


Title :   The Electrochemistry of Organophosphorus Compounds.


Descriptive Note : Final rept. 16 Sep 81-30 Sep 87,


Corporate Author : AUBURN UNIV AL


Personal Author(s) : Howard, James H


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a191081.pdf


Report Date : 20 Jan 1988


Pagination or Media Count : 12


Abstract : This final report summarizes research on investigations of the electrochemical behavior of organophosphorus compounds. The electrochemical formation of ylides from phosphomium salt reduction is reported. Diphosphines from reductions of halodiphenylphosphines and diphosphine dioxides form halodiphenyl phosphineoxides were observed. Electrocatalysis of dioxygen oxidation of phosphines, phosphinites, phosphonited and phosphites is also reported.


Descriptors :   *ELECTROCHEMISTRY , *ORGANIC PHOSPHORUS COMPOUNDS , CATALYSIS , DIOXIDES , PHOSPHINE , PHOSPHITES , REDUCTION , SYNTHESIS(CHEMISTRY) , ELECTROCATALYSTS , ELECTRON TRANSFER , PHOSPHONIUM COMPOUNDS , ABSTRACTS


Subject Categories : Organic Chemistry
      Physical Chemistry


Distribution Statement : APPROVED FOR PUBLIC RELEASE