Accession Number : ADA146828


Title :   Catalytic Oxidation by Transition Metal Ions in Zeolites.


Descriptive Note : Final rept. 1 Jun 81-31 May 84,


Corporate Author : TEXAS A AND M UNIV COLLEGE STATION DEPT OF CHEMISTRY


Personal Author(s) : Lunsford,J H


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a146828.pdf


Report Date : 28 Sep 1984


Pagination or Media Count : 9


Abstract : The regular cavities within zeolite form a unique environment for carrying out both stoichiometric and catalytic oxidation reactions. Transition metal ions such as molybdenum and cobalt may be introduced into zeolites, where they form complexes with oxidants and substrate ligands. The objectives of the research were (a) to understand oxidation reactions in zeolites at a molecular level and (b) to evaluate the potential of zeolites as catalysts in selective oxidation reactions.


Descriptors :   *IONS , *TRANSITION METALS , *CATALYSIS , *SILICATES , *OXIDATION REDUCTION REACTIONS , SUBSTRATES , CAVITIES , OXYGEN , PROPENES , LIGANDS , STOICHIOMETRY , MOLYBDENUM COMPOUNDS , PYRIDINES , COBALT COMPOUNDS , YTTRIUM , ADDITION REACTIONS , MOLECULAR COMPLEXES , EPOXIDATION


Subject Categories : Inorganic Chemistry
      Atomic and Molecular Physics and Spectroscopy


Distribution Statement : APPROVED FOR PUBLIC RELEASE