Accession Number : ADA136949


Title :   Electrochemistry of Anilines. II. Oxidation to Dications, Electrochemical and uv/vis Spectroelectrochemical Investigation.


Descriptive Note : Technical rept.,


Corporate Author : UTAH UNIV SALT LAKE CITY DEPT OF CHEMISTRY


Personal Author(s) : Speiser,B ; Rieker,A ; Pons,S


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a136949.pdf


Report Date : 06 Jan 1984


Pagination or Media Count : 62


Abstract : The electrochemical oxidation of 2,6-di-tert-butyl-4-R-anilines (R = C6H5, p-OCH3-C6H4 and p-N(CH3)2-C6H4) at the potentials of the second peak has been investigated. Dications could be observed and characterized by electroanalytical and spectroelectrochemical means. The cyclic voltammogram of the methoxy compound has been simulated by the orthogonal collocation method. Products of bulk electrolysis have been identified. Two different sites of attack in the case of the methoxy compound were found.


Descriptors :   *Electrochemistry , *Oxidation , *Anilines , *Spectroscopy , Chemical analysis , Specular reflection , Voltammetry , Simulation , Methodology , Electrolysis , Cations


Subject Categories : Organic Chemistry
      Atomic and Molecular Physics and Spectroscopy


Distribution Statement : APPROVED FOR PUBLIC RELEASE