Accession Number : AD1041346

Title :   Base Stability of Aminocyclopropeniums

Descriptive Note : Technical Report,01 Sep 2016,30 Sep 2017

Corporate Author : US Army Research Laboratory, Weapons and Materials Research Directorate Adelphi United States

Personal Author(s) : Baranoski,MyVan ; Beyer,Frederick L ; Lambeth,Robert ; Zander,Nicole

Full Text :

Report Date : 01 Nov 2017

Pagination or Media Count : 16

Abstract : Cyclopropenium cations with differing amino-functional groups were synthesized and tested for their utility in anion exchange membranes for alkaline fuel cells. A series of aminocyclopropeniums were synthesized and their base stability probed in situ using time-resolved proton nuclear magnetic resonance (1H NMR) under conditions designed to mimic those encountered in alkaline fuel cells to test their utility in anion exchange membranes. While the aminocyclopropeniums showed poor base stability, the cyclopropenium cation may have beneficial properties in neutral pH applications such as antimicrobial fabrics and coatings.

Descriptors :   alkaline fuel cells , nuclear magnetic resonance , hydroxides , chemical stability , flow batteries , high vacuum , hydrolysis , ionic liquids , organic solvents , ANION EXCHANGE , CATIONS , physical properties

Subject Categories : Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE