Accession Number : AD0466967


Title :   RESEARCH ON SYNTHESIS OF UNSATURATED FLUOROCARBON COMPOUNDS


Descriptive Note : Technical Report,01 Oct 1964,31 Mar 1965


Corporate Author : FLORIDA UNIV GAINESVILLE GAINESVILLE United States


Personal Author(s) : Tarrant, Paul ; Perry, Doug ; Tandon, Jai ; Wright, Alan ; Misaki, Susumu


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/466967.pdf


Report Date : 31 Mar 1965


Pagination or Media Count : 43


Abstract : A study has been made for producing perfluoroallyl bromide and iodide. The latter olefin reacted with alcohols to produce ethers such as CF(sub3)-CH(sub2)OCF(sub2)CF=CF(sub2). Attempts to prepare [CF(sub2)=CFCH(sub2)CH(sub2)CH(sub2)](sub2)O from the allyl ethers have been carried out but cyclic ethers were formed. An investigation of the radical addition of CF(sub3)CF(sub2)CCl(sub3), CF(sub2)ClCF(sub2)-CCl(sub3), CFClBrCFClBr and CCI(sub3)CF(sub2)CFClBr with various olefins has been initiated. Studies of the preparation of perfluoroalkane enoyides have also been initiated.


Descriptors :   (HALOGENATED HYDROCARBONS , FLUORINE COMPOUNDS) , (FLUORINE COMPOUNDS , HALOGENATED HYDROCARBONS) , (ALKENES , FLUORINE COMPOUNDS) , SYNTHESIS(CHEMISTRY) , BROMINE COMPOUNDS , IODINE COMPOUNDS , ETHERS , OXYGEN HETEROCYCLIC COMPOUNDS , LITHIUM COMPOUNDS , SILANES , INFRARED SPECTRA , NUCLEAR MAGNETIC RESONANCE , CATALYSTS , ALUMINUM COMPOUNDS , ZINC , ELASTOMERS


Subject Categories : Organic Chemistry
      Inorganic Chemistry


Distribution Statement : APPROVED FOR PUBLIC RELEASE