Accession Number : AD0466120


Title :   NITROSO RUBBER RESEARCH, DEVELOPMENT AND PRODUCTION


Descriptive Note : Technical Report,27 Feb 1963,31 May 1963


Corporate Author : THIOKOL CORP TRENTON NJ TRENTON United States


Personal Author(s) : Fein,Marvin M


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/466120.pdf


Report Date : 31 May 1963


Pagination or Media Count : 29


Abstract : The preparation of trifluoroacetyl nitrite by the interaction of trifluoroacetic anhydride and dinitrogen trioxide has been effected by replicate, small scale batches. Exploratory solution pyrolyses of the nitrite indicate that decarboxylation occurs at temperatures of 145 C or greater. Trifluoronitrosomethane was the major product. Small quantities of nitrosyl fluoride (FNO), for the synthesis of improved low temperature nitroso rubbers, were prepared by pyrolysis of nitrosyl tetrafluoroborate (NOBF4) and sodium fluoride at 250 C.


Descriptors :   (SYNTHETIC RUBBER , SYNTHESIS(CHEMISTRY)) , (FLUORINE COMPOUNDS , SYNTHESIS(CHEMISTRY)) , (ORGANIC NITROGEN COMPOUNDS , SYNTHESIS(CHEMISTRY)) , VULCANIZATES , HALOGENATED HYDROCARBONS , NITROGEN COMPOUNDS , OXYGEN COMPOUNDS , POLYMERS , COPOLYMERIZATION , STABILITY , COMPATIBILITY , TENSILE PROPERTIES , PYROLYSIS , TRANSITION TEMPERATURE


Distribution Statement : APPROVED FOR PUBLIC RELEASE