Accession Number : AD0454740


Title :   PYROLYSIS OF FLUORINATED ORGANIC COMPOUNDS. I. THE PYROLYSIS OF 1,2-DIBROMO-1-CHLORO-1,2,2-TRIFLUOROETHANE AND SOME RELATED HALOGENATED ETHANE DERIVATIVES,


Corporate Author : COLORADO UNIV BOULDER


Personal Author(s) : Park,J. D. ; Lamb,R. W. ; Lacher,J. R.


Report Date : 17 JAN 1964


Pagination or Media Count : 5


Abstract : The synthesis of various halogenated ethane derivatives was performed by the pyrolysis of CF2Br-CFC1Br and other similar compounds. The reactions were carried out in a platinum-lined tube at temperatures ranging from 350 to 600 C alone and in the presence of nitric oxide or bromine. Various products were isolated and identified. A mechanism is postulated for the reaction. (Author)


Descriptors :   (*HALOGENATED HYDROCARBONS, PYROLYSIS), (*FLUORINE COMPOUNDS, PYROLYSIS), (*PYROLYSIS, HALOGENATED HYDROCARBONS), BROMINE COMPOUNDS, CHLORINE COMPOUNDS, CHEMICAL BONDS, DISSOCIATION, ENERGY, NITROGEN COMPOUNDS, OXIDES, BROMINE


Distribution Statement : APPROVED FOR PUBLIC RELEASE