Accession Number : AD0430478


Title :   STUDIES IN ION SOLVATION IN MIXED SOLVENTS.


Descriptive Note : Final technical rept., 1 Dec 62-30 Nov 63,


Corporate Author : BIRKBECK COLL LONDON (ENGLAND)


Personal Author(s) : Feakins,D


Report Date : 30 Nov 1963


Pagination or Media Count : 50


Abstract : Using the appropriate chemical cells, the free energies to transfer of the pairs of ions H(+)Br (-) and H(+)I(-) in the standard state have been determined for transfers from water to 20% mixtures of dioxan and water at 25 degrees. A byproduct of the measurements is the dissociation constant of boric acid in the mixed solvent. Considerable experimental difficulties have been encountered and overcome in these measurements. (Author)


Descriptors :   *SOLVATES , *ELECTROLYTIC CELLS , MIXTURES , ELECTROCHEMISTRY , IONS , SOLVATION , ALCOHOLS , WATER , SOLVENTS , ELECTROLYTES , HYDROGEN COMPOUNDS , CHLORIDES , BROMIDES , IODIDES , HYDROXIDES , SODIUM COMPOUNDS , LITHIUM COMPOUNDS , ELECTRODES , SILVER , HYDROGEN , OXYGEN HETEROCYCLIC COMPOUNDS , DISSOCIATION , BORIC ACID , CHEMICAL EQUILIBRIUM , SOLUTIONS(MIXTURES)


Distribution Statement : APPROVED FOR PUBLIC RELEASE