Accession Number : AD0010113


Title :   CYLIC POLYOLEFINS. XXIX. CYCLOOCTATETRAENE DERIVATIVES FROM COPOLYMERIZATION AND SIDE CHAIN MODIFICATION


Corporate Author : MASSACHUSETTS INST OF TECH CAMBRIDGE


Personal Author(s) : COPE, ARTHUR C ; PIKE, RONALD M


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/010113.pdf


Report Date : 23 Mar 1953


Pagination or Media Count : 22


Abstract : New cyclooctatetraenes were prepared by copolymerization of acetylene with monosubstituted acetylenes or by reactions of functional groups in the side chains of the cyclooctatetraenes. The derivatives included gamma cyclooctatetraenylpropyl alcohol from 4-pentyn-1-ol, gamma- cyclooctatetraenylpropyl cyanide from 5-hexynenitrile, cyclooctateraenylmethylcarbon from 3-butyn-2-ol, cyclooctatetraenyl methyl ketone from 3-butyn-2-one, cyclooctatetraenyldimethylcarbinol from 2-methyl-3- butyn-2-ol. Physical and chemical evidence of the structures were obtained.


Descriptors :   *PHYSICAL PROPERTIES , COPOLYMERIZATION , ACETYLENE


Subject Categories : Physical Chemistry


Distribution Statement : APPROVED FOR PUBLIC RELEASE